Considering the non-ideal factors of the actual impedance matching network, and in order to achieve low Standing Wave Ratio (SWR) and high transmission efficiency, an impedance matching method for radio frequency antenna was proposed based on Dual-aimed Chaotic Particle Swarm Optimization (DCPSO) algorithm. The experimental results of single-frequency impedance matching obtained by DCPSO proves that SWR and output power performance are improved compared with Particle Swarm Optimization (PSO). Combined with real frequency method, broadband impedance matching experiments were done with working band of 2G, 3G and 4G mobile technologies, results show that the entire band can get good results with impedance matching transmission efficiency.